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This paper investigates the magnetocaloric effect (MCE) in a series of 6H-perovskite compounds, Ba3RRu2O9, where R represents different rare-earth elements (Ho, Gd, Tb, Nd). The study is significant because it explores the MCE in a 4d-4f correlated system, revealing intriguing behavior including switching between conventional and non-conventional MCE, and positive MCE in the Nd-containing compound. The findings contribute to understanding the interplay of magnetic ordering and MCE in these complex materials, potentially relevant for magnetic refrigeration applications.
Reference

The heavy rare-earth members exhibit an intriguing MCE behavior switching from conventional to non-conventional MCE.